DISPERSIBILITY OF NANOCRYSTALLINE CELLULOSE IN ORGANIC SOLVENTS

Authors

  • Марина (Marina) Игоревна (Igorevna) Воронова (Voronova) G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
  • Олег (Oleg) Валентинович (Valentinovich) Суров (Surov) G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
  • Наталья (Natal'ya) Викторовна (Viktorovna) Рублева (Rubleva) G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
  • Наталья (Natal'ya) Евгеньевна (Evgenievna) Кочкина (Kochkina) G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
  • Анатолий (Anatoliy) Георгиевич (Georgievich) Захаров (Zakharov) G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

DOI:

https://doi.org/10.14258/jcprm.2019014240

Keywords:

nanocrystalline cellulose, re-dispersibility, particle size

Abstract

Aqueous suspensions of nanocrystalline cellulose (NCC) were obtained by sulfuric acid hydrolysis using the standard procedure. Suspensions, films and airgel of NCC were characterized by various methods: the degree of polymerization was determined, elemental analysis was carried out, the degree of crystallinity and crystallite size were calculated on the basis of X-ray data, the morphology of NCC aerogels was studied using scanning electron microscopy. The particle size of the NCC was determined using a transmission electron microscope, a scanning atomic-force microscope and the method of dynamic light scattering. NFC hydrosols with different pH were used to prepare lyophilized NCC samples. From NCC hydrosols with pH 2.2, by gradual replacement of water with an organic solvent, NCC organogels with acetone, acetonitrile and ethanol were obtained.

The process of dispersion of lyophilized NCC and NCC organogels (acetone, acetonitrile and ethanol) in water and in 11 organic solvents was investigated. The effect of the pH of the initial aqueous suspension of the NCC and the solvent forming the NCC organogel on the repeated dispersibility of the NCC is shown. The optimum pH value of the initial aqueous suspension of NCC was determined, which determines the maximum dispersibility of the lyophilized samples in each specific solvent. It was shown that dispersion of acetone, acetonitrile and ethanol organogels in most of the solvents studied occurs with the formation of particles less than 100 nm.

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Author Biographies

  • Марина (Marina) Игоревна (Igorevna) Воронова (Voronova), G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

    кандидат химических наук, старший научный сотрудник

  • Олег (Oleg) Валентинович (Valentinovich) Суров (Surov), G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

    кандидат химических наук, старший научный сотрудник

  • Наталья (Natal'ya) Викторовна (Viktorovna) Рублева (Rubleva), G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

    научный сотрудник

  • Наталья (Natal'ya) Евгеньевна (Evgenievna) Кочкина (Kochkina), G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

    кандидат технических наук, старший научный сотрудник

  • Анатолий (Anatoliy) Георгиевич (Georgievich) Захаров (Zakharov), G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

    доктор химических наук, профессор, заведующий лабораторией

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Published

2019-03-06

Issue

No. 1 (2019)

Section

Biopolymers of plants

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How to Cite

[1]
2019. DISPERSIBILITY OF NANOCRYSTALLINE CELLULOSE IN ORGANIC SOLVENTS. chemistry of plant raw material. 1 (Mar. 2019), 39–50. DOI:https://doi.org/10.14258/jcprm.2019014240.

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